When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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| DATAFILE: | CFCl3(CFC-11)_JPL-2015(2015)_298K_174-260nm(rec).txt |
| NAME: | fluorotrichloromethane (CFC-11) |
| FORMULA: | CFCl3(CFC-11) |
| AUTHOR(YEAR): | JPL-2015(2015) |
| T: | 298K |
| λ: | 174-260nm(rec) |
| BIBLIOGRAPHY: |
J. B. Burkholder, S. P. Sander, J. Abbatt, J. R. Barker, R. E. Huie, C. E. Kolb, M. J. Kurylo, V. L. Orkin, D. M. Wilmouth, and P. H. Wine, "Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 18",
JPL Publication 15-10, Jet Propulsion Laboratory, Pasadena, 2015 http://jpldataeval.jpl.nasa.gov
|
| COMMENTS: | JPL-2015(2015) recommendation:
170-188 nm, data of
P. C. Simon, D. Gillotay, N. Vanlaethem-Meurée, and J. Wisemberg, Ultraviolet absorption cross-sections of chloro- and chlorofluoro-methanes at stratospheric temperatures, J. Atmos. Chem. 7, 107-135 (1988); DOI: 10.1007/BF00048042,
190-230 nm, parameterization of
M. R. McGillen, E. L. Fleming, C. H. Jackman, and J. B. Burkholder, CFCl3 (CFC-11), "UV absorption spectrum temperature dependence measurements and the impact on its atmospheric lifetime and uncertainty," Geophys. Res. Lett., 40, 4772–4776 (2013); DOI: 4710.1002/grl.50915,
235-260 nm; data of
C. Hubrich and F. Stuhl, "Ultraviolet absorption of some halogenated methanes and ethanes of atmospheric interest", J. Photochem. 12, 93-107 (1980); DOI: 10.1016/0047-2670(80)85031-3
The parameterization of the temperature dependence valid over the 190−230 nm wavelength range and 216−296 K temperature range:
log10 (σ(λ,T)) = ∑i Ai (λ - 200)i + (296 – T) ∑i Bi (λ - 200)i with the following parameters Ai and Bi:
----------------------------------------------------------
i Ai Bi
----------------------------------------------------------
0 -18.1863 0.0002656
1 -0.0528 4.228×10-5
2 -0.001126 1.4027×10-6
3 -3.0552×10-5 6.44645×10-7
4 2.24126×10-6 -3.8038×10-8
5 -3.2064×10-8 5.99×10-10
is recommended |
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