The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

https://www.uv-vis-spectral-atlas-mainz.org, https://uvvis.mpch-mainz.gwdg.de

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Halogeno-alkanes+radicals / Freons-CFC(C,F,Cl) / CFCl3(CFC-11) / JPL-2015(2015)_298K_174-260nm(rec)

DATAFILE: CFCl3(CFC-11)_JPL-2015(2015)_298K_174-260nm(rec).txt
NAME: fluorotrichloromethane (CFC-11)
FORMULA: CFCl3(CFC-11)
AUTHOR(YEAR): JPL-2015(2015)
T: 298K
λ: 174-260nm(rec)
BIBLIOGRAPHY: J. B. Burkholder, S. P. Sander, J. Abbatt, J. R. Barker, R. E. Huie, C. E. Kolb, M. J. Kurylo, V. L. Orkin, D. M. Wilmouth, and P. H. Wine, "Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 18", JPL Publication 15-10, Jet Propulsion Laboratory, Pasadena, 2015 http://jpldataeval.jpl.nasa.gov
COMMENTS: JPL-2015(2015) recommendation:

170-188 nm, data of

P. C. Simon, D. Gillotay, N. Vanlaethem-Meurée, and J. Wisemberg, Ultraviolet absorption cross-sections of chloro- and chlorofluoro-methanes at stratospheric temperatures, J. Atmos. Chem. 7, 107-135 (1988); DOI: 10.1007/BF00048042,

190-230 nm, parameterization of

M. R. McGillen, E. L. Fleming, C. H. Jackman, and J. B. Burkholder, CFCl3 (CFC-11), "UV absorption spectrum temperature dependence measurements and the impact on its atmospheric lifetime and uncertainty," Geophys. Res. Lett., 40, 4772–4776 (2013); DOI: 4710.1002/grl.50915,

235-260 nm; data of

C. Hubrich and F. Stuhl, "Ultraviolet absorption of some halogenated methanes and ethanes of atmospheric interest", J. Photochem. 12, 93-107 (1980); DOI: 10.1016/0047-2670(80)85031-3

The parameterization of the temperature dependence valid over the 190−230 nm wavelength range and 216−296 K temperature range:

log10 (σ(λ,T)) = ∑i Ai (λ - 200)i + (296 – T) ∑i Bi (λ - 200)i

with the following parameters Ai and Bi:

----------------------------------------------------------
i    Ai        Bi
----------------------------------------------------------

0  -18.1863      0.0002656
1   -0.0528       4.228×10-5
2   -0.001126      1.4027×10-6
3   -3.0552×10-5      6.44645×10-7
4    2.24126×10-6     -3.8038×10-8
5   -3.2064×10-8      5.99×10-10

is recommended

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