The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

https://www.uv-vis-spectral-atlas-mainz.org, https://uvvis.mpch-mainz.gwdg.de

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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Contact, Imprint, Acknowledgements

When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Halogeno-alkanes+radicals / Freons-CFC(C,F,Cl) / CFCl3(CFC-11) / SPARC(2013)_298K_121.567nm(rec)

DATAFILE: CFCl3(CFC-11)_SPARC(2013)_298K_121.567nm(rec).txt
NAME: fluorotrichloromethane (CFC-11)
FORMULA: CFCl3(CFC-11)
AUTHOR(YEAR): SPARC(2013)
T: 298K
λ: 121.567nm(rec)
BIBLIOGRAPHY: J.B. Burkholder, W. Mellouki, E.L. Fleming, C. George, D.E. Heard, C.H. Jackman, M.J. Kurylo, V.L. Orkin, W.H. Swartz, and T.J. Wallington, "Evaluation of Atmospheric Loss Processes: Photochemistry Supplement", SPARC Lifetimes Report (2013) – SPARC Report No. 6, Chapter 3: Supplement 4, 3S4-1 - 3S4-52 (2013); www.sparc-climate.org/publications/sparc-reports/
COMMENTS: Recommended absorption cross section at the Lyman-α wavelength with an estimated uncertainty factor p(298 K) = 1.20

The value is an average of the results of

J. Doucet, P. Sauvageau, and C. Sandorfy, "Vacuum ultraviolet and photoelectron spectra of fluoro-chloro derivates of methane", J. Chem. Phys. 58, 3708-3716 (1973); DOI: 10.1063/1.1679584,

R. Gilbert, P. Sauvageau, and C. Sandorfy," Vacuum ultraviolet absorption spectra of chlorofluoromethanes from 120 to 65 nm", J. Chem. Phys. 60, 4820-4824 (1974); DOI: V, and

D.P. Seccombe, R.P. Tuckett, H. Baumgärtel, and H.W. Jochims, "Vacuum-UV fluorescence spectroscopy of CCl3F, CCl3H and CCl3Br in the range 8-30 eV", Phys. Chem. Chem. Phys. 1, 773-782 (1999); DOI: 10.1039/A809422E,

linearly interpolated to 121.567 nm

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