The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

https://www.uv-vis-spectral-atlas-mainz.org, https://uvvis.mpch-mainz.gwdg.de

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany

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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013

Cross Sections / Halogeno-alkenes+radicals / Chlorofluoroalkenes / trans-CHCl=CHCF3 / Orkin(2014)_298K_166-226nm(2nm)

DATAFILE: trans-CHCl=CHCF3_Orkin(2014)_298K_166-226nm(2nm).txt
NAME: trans-1-chloro-3,3,3-trifluoropropene
FORMULA: trans-CHCl=CHCF3
AUTHOR(YEAR): Orkin(2014)
T: 298K
λ: 166-226nm(2nm)
BIBLIOGRAPHY: V.L. Orkin, L.E. Martynova, and M.J. Kurylo, "Photochemical properties of trans-1-chloro-3,3,3-trifluoropropene (trans-CHCl=CHCF3): OH reaction rate constant, UV and IR absorption spectra, global warming potential, and ozone depletion potential", J. Phys. Chem. A 118, 5263-5271 (2014); DOI: 10.1021/jp5018949
COMMENTS: Absorption measurements over the wavelength range of 165−300 nm using a single-beam apparatus consisting of a 1 m vacuum monochromator equipped with a 600 lines/mm grating. The radiation source was a Hamamatsu L1385 deuterium lamp, and the detector was a Hamamatsu R166 photomultiplier. Spectra were recorded at increments of 0.5 nm at a spectral slit width of 0.5 nm. The sample pressure between 2.7 Pa (0.02 Torr) and 45.3 kPa (340 Torr) was used to obtain the entire absorption spectrum.

Absorption cross sections at 2-nm intervals as listed in Table 2

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